This is something I have been trying lately if I have time on Tuesday's after a server restart. When a server is brought back up after maintenance on Tuesdays all of the Rare Named mobs are spawned. So you can easily go and kill these before anyone else.
On my server there is never anyone online those 4-5 hours after the server comes up. So that's prime time to find some Rare mobs. So far I have received several greens and a couple blues. Gotta get lucky and get that epic now
Here is a link listing of all Rare Mobs and their locations:
http://wow.allakhazam.com/dyn/mobs/rare.html
(Give lalami487 credit on the above link, found off a post he made 2 months ago)
Goodluck!
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