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I was grinding for lowbie loot in the Barrens the other day when i happened to notice that you can shoot a mob while looting a dead corpse. Just do as follows:
1. Kill a mob (obviously)
2. Target a different mob
3. Shoot an Arcane shot, Serpent Sting, or any other instant cast shot at the mob
4. Immediately after firing, loot the corpse; you should fire an autoshot as you loot
*note* You can only fire off 1 autoshot while looting; I suggest that you have a lot of free room in your inventory so you can autoshot/loot all without missing a beat
This has been tested by me personally and it's relatively easy to do; I find it helpful for those serious grinding sessions.
Good luck, people!