I'm assuming you have a function for MD5StringHash, yeah?
The Hex function is used to change a normal int to a hex value. What you want there would be this:
Code:
Dim BinMD5 As String = Convert.ToString(Convert.ToInt32(MD5StringHash(TextBox3.Text),16),2)
Breaking it down: You already have your MD5 string of Hex. The inner convert changes this to an int32 (from base 16). The outer changes this to binary (base 2). Convert = god when it comes to moving between arbitrary bases. ToInt32, you put what you're converting from. ToString, what you're converting to.