If there is anything I have missed out please let me know and I'll update it in
Addons
EveryQuest : Miscellaneous : WoWInterface Downloads
This is an insanely useful addon which keeps track of all the quests within a zone that you have or have not done, it allows you to check how many quests are left within a zone and prevents the nervous breakdown when you cant remember if you've done the quests in a certain zone or not
QuestHelper : Quest/Leveling/Reputation Mods : WoWInterface Downloads
Very known by the wow community in general unless you've been living under a rock, I personally find this to be better than the Blizzard built in version and it simplifies the tedious task of where you need to go for quests. This allows much less wasted time tracking and more time charging through the achievment
Personal Trick
A personal method that I used to make the process easier is to find the zone I'm currently doing on wowhead and use the features there to select either alliance or horde quest givers to be placed as ping marks on the map. By doing this it allows you to find and collect every quest possible from the various hubs and then simply complete them and their chains e.g. badlands for alliance
Badlands - Zone - World of Warcraft
Final words of advice
Do not attempt this achievement light heartily, it is an immense time saver and a quote from my friend after doing this would be...
"I suggest eatling a lot of mushrooms or having morphine injected on a regular basis to keep your mind from exploding, the single worst achievment I've ever attempted"
Take this achievement in moderation, there is no rush till cata with it being released on December 7th and The Loremaster will no doubt still be around when it's released just slightly different It is your last chance to see the quests as they are so go go if you like that!